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Soc. chim. France, 1971,461. A . Gaiffe and J . Castanet, Compt. , 1971, 272, C, 96. A. Gaiffe and J . Castanet, Compt. , 1970, 271, C, 1012. J. M . Coxon, R. P. Garland, and M. P. Hartshorn, Chem. , 1970, 1709 (Chem. Abs. 1971, 74, 142 073, summarizing this work, is incorrect). 217 J. M. Coxon, R. P. Garland, and M. P. Hartshorn, Austral. J . Chem. 1970, 23, 2531. J. M. Coxon, R. P. Garland, and M. P. Hartshorn, Austral. J . , 1971, 24, 1481. 2 1 4 J. R. Salmon and D. Whittaker, J . Chem. Suc.

111). d. d. of the pulegone epoxides has also been studied. '16 The reaction of pulegone and isopulegone (as well as carvone) with ethoxymethylmagnesium <: Q::. + / (154) I 0 0 A OCOPh '"' 1 ' ' l2 'I4 II I" ' + c: OCOPh A + COPh OCOPh + $5 Ph COPh V. Hach, E. C. Fryberg, and E. McDonald, Tetrahedrun Letters, 1971, 2629. M . R . Johnson and B . Rickborn, J . Org. , 1970, 35, 1041. T. Suga, K. Imamura, and T. Shishibori, Chem. , 1971, 126. T. M . Feeley and M. K . Hargreaves, J . Chem. (C), 1970, 1745.

Perez, D . Salgado, and E. Santos, Tetrahedrun Letters, 1970. 5069. Mono te rpenoids 31 chloride followed by formic acid has been shown to give 45 % of the 3-aldehyde (160), with only small amounts of the product (161) in which the double bond has been displaced to the 8-position; (161) is the main product from isopulegone (162). ' I 8 Reductive dimerization of pulegone affords the alcohol (164), which dehydrates with simultaneous Wagner-Meerwein rearrangement to the substituted hydrophenanthrene (165); this reaction and further reactions of (165) have been examined by Bartual and Pascual.

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